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Effect of intraveneous thrombolysis bridged endovascular thrombectomy with the solitaire stent retri
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The lanthanide-containing Single-molecule magnet(SMM)are attracting increasing attention due to strong magnetic anisotro......
For single-molecule magnets(SMMs),it cannot be ignored that the fast quantum tunneling of magnetization(QTM)process,whic......
Four Complexes of Mn(Ⅱ),Co(Ⅱ),Ni(Ⅱ)and Cu(Ⅱ)Based on 2-Morpholine-4-yl-4,6-di-pyrazol-1-yl-1,3,5-tri
Three azide bridged complexes,namely,[Mn2L2(N3)4(H2O)2](1),[Co2L2(N3)4]·(H2O)3(2)and[Ni2L2(N3...
<正> A new amperometric flow-through deteetor is designed for application to flow-injection analysis and continuous flow......
<正> The Hammett correlation has been successfully applied to electrophilic additions of the olefins. However, the corre......
High Efficieney Synthesis of Isotaetie Polypropylene and Linear Polyethylene Using a New C_2-symmetr
Ansa-Cyclohexyl-bis(4,5,6,7-tertrahydro-l-indenyl)zirconium dichloride(5)was used as catalyst for propylene and ethylene......
Three new cyanido-bridged heterometallic ReIVNiII and ReIVCuII one-dimensional systems were synthesized and extensively ......
Complexation of the planar multidentate ligand 3,5-bis-(2-hydroxyphenyl)pyrazole (H3L) with manganese chloride leads to ......
A new hexanuclear silver(I) compound containing thiosemicarbazones with groups of 1-naphthalene was synthesized and stru......
Structure and Luminescence Property of a Hexanuclear Silver(Ⅰ) Cluster Containing Benzaldehyde Thios
A new hexanuclear silver (I) compound 2 containing thiosemicarbazone with the group of benzene was synthesized and struc......
Cyanide-bridged complexes based on dinuclear Cu(Ⅱ)-M(Ⅱ) [M=Pb and Cu] building blocks: Synthesis, cr
Four cyanide-bridged heterometallic complexes {[CuPb(L 1 )][Fe III (bpb)(CN) 2 ]} 2 ·(ClO 4 ) 2 ·2H 2 O·2CH 3 CN (1),......
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The synthesis and molecular structure of a new dinuclear copper(Ⅰ) complex [Cu(dppb)(NO 3)] 2 are reported.The compound......
A Two-dimensional Gadolinium(Ⅲ) Coordination Polymer with 5-Hydroxynicotinatic Acid and Oxalate Liga
A new coordination polymer, [Gd(Ⅲ)(3-H-5-hydroxynicotinato)(ox)1.5(H2O)2]n, has been synthesized by a hydrothermal reac......
The two three-dimensional oxo-bridged lanthanides , with Ln=Ho3+ (1); Gd3+ (2), are isomorphous. They have layer-type st......
Enantioselective epoxidation of nonfunctionalized alkenes catalyzed by recyclable new homochiral bis
Three new homochiral bis-diamine-bridged bi-Mn(salen) complexes were synthesized. Their catalysis on asymmetric epoxidat......
Combination of Lindqvist-type Tungstovanadates and Transition Metal Clusters under Hydrothermal Cond
Two novel organic-inorganic heteropolyoxometalate compounds [{Cu(1,10- phen)OH}_2]_2[V_2W_4O_19]·6H_2O (1) and [Co(1,10......
A new coordination compound, [Pb(L)(adip)]2n (L=11-fluoro-dipyrido[3,2-a:2’,3’-c]phenazine and H2adip=adipic acid), ha......
Hydrothermal syntheses and characterization of three lanthanide coordination complexes constructed b
Two 1D coordination polymers [Ln2(dpdc)3(tpy)2·H2O]n [Ln=Nd 1, Yb 2, H2dpdc=2,2’-biphenyldicarboxylic acid and tpy= 2,......
Two couples of enantiomerically pure chiral cyano-bridged heterobimetallic one-dimensional (1D) chain complexes: [Mn((R,......
A tetranuclear Li 2 Cr 2 acetylide precursor complex, [Li(Tp)CrⅢ (C≡CSiMe 3 ) 2 (μ3 -pz)] 2 ·(n-pentane) 2 (Tp = hyd......
Two helical one-dimensional complexes [MnII(MeOH)4][MnIV(L·)2]·2MeOH (1) and [MnIII(salen)][MnIII(L)2] (2) (H2L = HON=......
Spin-canting and weak ferromagnetism in two novel 1D alternating chains with single cis-end-to-end a
By combining trans-4-styrylprydine (tsp) with azide system, we obtained two rare 1D cis-EE-azido-bridged compounds of [M......
One-dimensional lanthanide complexes bridged by nitronyl nitroxide radical ligands with non-chelatin
A series of new lanthanide-radical complexes [{Ln(hfac)3}2(NITPhIM)2] (Ln = Nd (1), Eu (2), Tb (3), Er (4); hfac = hexaf......
Synthesis and characterization of carbon-bridged bis(phenolate) lanthanum alkoxides and their cataly
Four lanthanum alkoxides stabilized by a carbon-bridged bis(phenolate) ligand were synthesized and their catalytic behav......
Ferromagnetic interactions in EO-azido-bridged binuclear transition metal(Ⅱ) systems: Syntheses, cry
Three new isostructural binuclear transition metal complexes with azido ion and 1,2-bis(3-(pyridin-2-yl)-1H-pyrazol-1-yl......
M_2(pbtcH)(phen)_2(H_2O)_2[M(Ⅱ)=Co,Ni]:Mixed-ligated metal phosphonates based on 5-phosphonatophenyl
Two new mixed-ligated metal phosphonates,M_2(pbtcH)(phen)_2(H_2O)_2[M(II) = Co(1),Ni(2)](pbtcHr,= 5-phosphonatophenyl-1,......
A Novel 3D Heterobimetallic Cyano-bridged Coor- dination Polymer {(NH_4)_2[Cd(H_2O)Fe(CN)_6]}_n:Synt
A novel heterobimetallic coordination polymer, {(NH4)2[Cd(H2O)Fe(CN)6]}n 1, has been synthesized by using the slow diffu......
Synthesis and Crystal Structures of Two Di-Cu(Ⅱ) Complexes Based on an Asymmetric Dinucleating Ligan
Two new dicopper(II) complexes [Cu2L(OAc)2](ClO4)·H2O(1) and [Cu2L(BPP)2]-(ClO4)(2) using an asymmetric dinucleating li......
Boron- and silicon-bridged bis(diphenylphosphino)-type ligands for chromium-catalyzed ethylene oligo
PNP-type ligands showed very good property in the catalytic systems of PNP/Cr(Ⅲ)/methylaluminoxane(MAO)for ethylene sel......
Visible-light photoredox-mediated oxidation of N-methyl tertiaryamines under catalyst free condition
Mediated by visible light-induced photoredox catalysis and free of other catalysts,a new and efficient synthesis of meth......
Synthesis,Crystal Structure and MMCT Property of a New Mixed-valence Cyanide-bridged Binuclear Compl
A new mixed-valence cyanide-bridged complex, Br3Fe(μ-NC)RuBr(dppm)2(dppm = bis(diphenylphosphino)methane), was obtained......
Bimetallic amine-bridged bis(phenolate) lanthanide aryloxides and alkoxides: synthesis, characteriza
A series of neutral bimetallic lanthanide aryloxides p-C6H4[OLnL(THF)n]2 [Ln = Y(1), Yb(2), Sm(3)(n = 1) and La(4)(n = 2......
Efficient Synthesis of Complex Bridged 1,3-Oxazabicycles via Reactions of N-Alkyl-1,10-phenanthrolin
Complex bridged 1,3-oxazabicycles and 1,4-disubstituted 1,10-phenanthroline derivatives were efficiently prepared by the......
Synthesis and Characterization of a Two-dimensional Cadmium(Ⅱ) Metal Organic Framework with Fes Topo
A new Cd(Ⅱ) coordination polymer, {[Cd(Hnbta)(L)]·H2O}n(L = 1,4-bis(5,6-dimethylbenzimidazol-1-yl)butane), H3nbta= 5-n......
Poly[(μ4-2,6-dimethylpyridine-3,5-dicarboxylato)dihydrate]diaqualead(II)] (1) exhi- bits a two-dimensional (2-D) layer ......
Chiral cyanide-bridged 1D Fe~Ⅲ-Mn~Ⅲ heterobimetallic chains: Synthesis, structures and magnetic prop
Two couples of enantiomerically pure chiral cyano-bridged heterobimetallic one-dimensional (1D) chain complexes: [Mn((R,......
A new binuclear copper complex, [Cu2L2(pht)2]2·H2O(Hpht = 5,5-diphenylhydantoin, i.e. phenytoin; L = 2-diethylaminoetha......
Synthesis and Crystal Structure of a Novel Chiral 3D Metal-organic Framework Based on an N-methyl Su
A chiral 3D metal-organic framework [CdL]·DMSO·H2O(1) was constructed by an N-methyl substituted salan ligand(H2L), an......
Theoretical Studies on the M-M Bonding in Complexes [M_2Cl_4L_2] and [M_2Cl_7L]- (M = Mo, Re; L = Ph
The structures of complexes [MⅡ2Cl4L2] and [MⅢ2Cl7L]- (M = Mo, Re; L = Ph2Ppy, (Ph2P)2py) were calculated by using den......
Hydrothermal Synthesis, Crystal Structure and Fluorescence Properties of a Three-dimensional Triply-
The novel complex [Zn2(Mba)3(Phen)2EtOH)]·ClO4 (Hmba=methoxybenzoic acid, Phen=1,10-phenanthroline, EtOH=ethanol) was s......
Two cationic iridium(III) complexes, [(pqcm)2Ir(pybz)](PF6) (Ir1) and [(pqcm)2Ir(apybz)](PF6) (Ir2) (pqcmH=2-phenyl-quin......
Synthesis, Structure and Comparison of Luminescent Property between Two Hexanuclear Silver(Ⅰ) Thiose
A new silver(Ⅰ) compound 4 containing thiosemicarbazone with group 2-quinoline was synthesized and structurally charact......
Syntheses and Crystal Structures of Two One-dimensional Cobalt(Ⅱ) Compounds with the Flexible Dipyri
Two one-dimensional cobalt(Ⅱ) compounds {[Co(Hbpma)(H2O)4 ] 2 ·3SO 4 ·4.5H2O} n1 and {[Co(Hbpma)(NCS) 3 (H2O)]·2.85H......
Hydrothermal Synthesis,Structure and Characterization of a New 2D Co(Ⅱ) Coordination Polymer Based o
A 1D supramolecular compound [dmbbbi](1) and a 2D cobalt coordination polymer [Co(dmbbbi)(ox)] 2(2) [dmbbbi=1,1-(1,4-but......
Structure and Luminescence Property of a Hexanuclear Silver(I) Cluster Containing Pyridine-3-carboxa
A new hexanuclear silver(I) compound containing thiosemicarbazone with group of 3-pyridine was synthesized and structura......
Two novel and well-defined polyhedral oligomeric silsesquioxanes(POSS) with two same Si_8O_(12) cores and a reactive NH ......
Detailed studies of the structures, magnetic properties and photodimerization of a series of formato-bridged MOFs with t......